Mutual Induced Coordination in Halogen-Bonded Anionic Assemblies with (6.3) Cation-Templated Topologies |
Chem. Commun. 2008, 1635-1637 |
P. Metrangolo, F. Meyer, T. Pilati, G. Resnati, G. Terraneo |
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Honeycomb-like anion network made by cation-templated halogen bonding self-assembly |
A mutual induced fitting process elicits the tridentate coordination profile of both 1,3,5-trifluoro-2,4,6-triiodobenzene and I‾ ions resulting in cation-templated anionic (6.3) networks.
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