Mutual Induced Coordination in Halogen-Bonded Anionic Assemblies with (6.3) Cation-Templated Topologies
Chem. Commun. 2008, 1635-1637
P. Metrangolo, F. Meyer, T. Pilati, G. Resnati, G. Terraneo
Honeycomb-like anion network made by cation-templated halogen bonding self-assembly
Honeycomb-like anion network made by cation-templated halogen bonding self-assembly
ABSTRACT
A mutual induced fitting process elicits the tridentate coordination profile of both 1,3,5-trifluoro-2,4,6-triiodobenzene and I‾ ions resulting in cation-templated anionic (6.3) networks.