Hydrogen and halogen bonding drive the orthogonal self-assembly of an organic framework possessing 2D channels
Chem. Commun., 2012, 48, 8207-8209
J. Marti-Rujas, L. Colombo, J. Lu, A. Dey, G. Terraneo, P. Metrangolo, T. Pilati, G. Resnati
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ABSTRACT
Orthogonal self-assembly of an open organic framework showing 2D channels has been obtained by combining hydrogen and halogen bonding. The framework is able to host various guest molecules with a diverse set of steric demands and substitution patterns, and survives single-crystal-to-single-crystal guest exchanges from liquid and gas phases.