Metric Engineering of Perfluorocarbon-Hydrocarbon Layered Solids Driven by the Halogen Bonding
Chem. Commun. 2004, 1492
P. Metrangolo, T. Pilati, G. Resnati, A. Stevenazzi
Layered halogen-bonded co-crystal between 1,4-dicyanobutane and 1,8-diiodoperfluorooctane
Layered halogen-bonded co-crystal between 1,4-dicyanobutane and 1,8-diiodoperfluorooctane
ABSTRACT
The halogen bonding driven self-assembly of 1,4 dicyanobutane and 1,6 dicyanohexane with a range of perfluorinated telechelic diiodoalkanes yields layered 1D, infinite chain co-crystals. The structure and metrics of these co-crystals are remarkably predictable.