Spontaneous Resolution in a Halogen Bonded Supramolecular Architecture |
Chem. Commun. 2005, 12, 1534 |
H. Neukirch, E. Guido, R. Liantonio, P. Metrangolo, T. Pilati, G. Resnati |
Halogen bonding based enantiopure co-crystal between 1,8-diiodoperfluorooctane and N,N,N,N-tetramethyl-p-phenylenediamine. The long perfluorinated chain adopts an unusual gauche arrangement. |
Halogen bonding driven self-assembly of 1,8-diiodoperfluorooctane and N,N,N,N-tetramethyl-p-phenylenediamine induces the formation of a chiral and enantiopure co-crystal.
|