Spontaneous Resolution in a Halogen Bonded Supramolecular Architecture
Chem. Commun. 2005, 12, 1534
H. Neukirch, E. Guido, R. Liantonio, P. Metrangolo, T. Pilati, G. Resnati
Halogen bonding based enantiopure co-crystal between 1,8-diiodoperfluorooctane and N,N,N,N-tetramethyl-p-phenylenediamine. The long perfluorinated chain adopts an unusual gauche arrangement.
Halogen bonding based enantiopure co-crystal between 1,8-diiodoperfluorooctane and N,N,N,N-tetramethyl-p-phenylenediamine. The long perfluorinated chain adopts an unusual gauche arrangement.
ABSTRACT
Halogen bonding driven self-assembly of 1,8-diiodoperfluorooctane and N,N,N,N-tetramethyl-p-phenylenediamine induces the formation of a chiral and enantiopure co-crystal.