Haloperfluorocarbons: Versatile Tectons in Halogen Bonding Based Crystal Engineering |
ACS Symp. Ser. n. 911 on ?Fluorine Containing Synthons?, Ed. V. A. Soloshonok, Oxford University Press/American Chemical Society, Washington D.C. 2005, 513. |
P. Metrangolo, F. Meyer, G. Resnati, M. Ursini |
Fluorine Containing Synthons |
Through the description of numerous examples, we have shown how iodo- and bromo-PFCs work as effective electron accepting species when interacting with a wide variety of lone pair possessing atoms, either neutral or anionic. Halo-PFCs are therefore versatile tectons for the elaboration of supramolecular architectures by halogen bonding.
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