Methylisonicotinate behaves as monotopic or heteroditopic electron donor in halogen bonding-based crystal engineering. This can be controlled by the used starting modules? stoichiometry in solution.
| Solution Stoichiometry Determines Crystal Stoichiometry in Halogen-Bonded Supramolecular Complexes |
| CrystEngComm 2007, 9, 341 |
| L. Russo, S. Biella, M. Lahtinen, R. Liantonio, P. Metrangolo, G. Resnati, K. Rissanen |
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| Ellipsoid plots (50% probability) of the 1:1 (3a) and the 2:1 (3b) supramolecular complexes MINC ? DITFB. Hydrogens omitted. |
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Methylisonicotinate behaves as monotopic or heteroditopic electron donor in halogen bonding-based crystal engineering. This can be controlled by the used starting modules? stoichiometry in solution.
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