Tuning Second-Order NLO Responses through Halogen Bonding |
Chem. Commun. 2007, 2590 |
E. Cariati, A. Forni, S. Biella, P. Metrangolo, F. Meyer, G. Resnati, S. Righetto, E. Tordin, R. Ugo |
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Optimized geometry of the halogen-bonded complex between N,N-dimethyl-4-[(E)-2-(2,3,5,6-tetrafluoro-4-iodophenyl)vinyl]aniline and DMF. |
As a function of the ability of the solvent to behave as acceptor of halogen bonding, the NLO-phores under study give rise to mubeta values ranging from +192 x 10-48 esu to -465 x 10-48 esu.
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