Tuning Second-Order NLO Responses through Halogen Bonding
Chem. Commun. 2007, 2590
E. Cariati, A. Forni, S. Biella, P. Metrangolo, F. Meyer, G. Resnati, S. Righetto, E. Tordin, R. Ugo
Optimized geometry of the halogen-bonded complex between N,N-dimethyl-4-[(E)-2-(2,3,5,6-tetrafluoro-4-iodophenyl)vinyl]aniline and DMF.
Optimized geometry of the halogen-bonded complex between N,N-dimethyl-4-[(E)-2-(2,3,5,6-tetrafluoro-4-iodophenyl)vinyl]aniline and DMF.
ABSTRACT
As a function of the ability of the solvent to behave as acceptor of halogen bonding, the NLO-phores under study give rise to mubeta values ranging from +192 x 10-48 esu to -465 x 10-48 esu.