Perfluoroalkylation of Aromatic Compounds with Perfluorodiacyl Peroxides |
Chem. Today 2007, 25, 23 |
G. Resnati, I. Wlassics, M. Sansotera, P. Metrangolo, W. Navarrini |
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Proposed mechanism for perfluoroalkylation of aromatic rings by perfluorodiacyl peroxides. |
Perfluoroalkylation of aromatics obtained by perfluorodiacyl peroxides decomposition has been studied and rationalized. Products and by-products formed are in agreement with the proposed free radical/one electron transfer mechanism.
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