Perfluoroalkylation of Aromatic Compounds with Perfluorodiacyl Peroxides
Chem. Today 2007, 25, 23
G. Resnati, I. Wlassics, M. Sansotera, P. Metrangolo, W. Navarrini
Proposed mechanism for perfluoroalkylation of aromatic rings by perfluorodiacyl
peroxides.
Proposed mechanism for perfluoroalkylation of aromatic rings by perfluorodiacyl peroxides.
ABSTRACT
Perfluoroalkylation of aromatics obtained by perfluorodiacyl peroxides decomposition has been studied and rationalized. Products and by-products formed are in agreement with the proposed free radical/one electron transfer mechanism.